A Breathing Atom‐Transfer Radical Polymerization: Fully Oxygen‐Tolerant Polymerization Inspired by Aerobic Respiration of Cells
نویسندگان
چکیده
منابع مشابه
Nanostructured hybrid hydrogels prepared by a combination of atom transfer radical polymerization and free radical polymerization.
A new method to prepare nanostructured hybrid hydrogels by incorporating well-defined poly(oligo (ethylene oxide) monomethyl ether methacrylate) (POEO(300)MA) nanogels of sizes 110-120 nm into a larger three-dimensional (3D) matrix was developed for drug delivery scaffolds for tissue engineering applications. Rhodamine B isothiocyanate-labeled dextran (RITC-Dx) or fluorescein isothiocyanate-lab...
متن کاملLiving Radical Polymerization: a Review
Free radical polymerization is one of the most widely employed polymerization techniques. This technique is applied to prepare latexes to be used in paints, high molecular weight poly (methyl methacrylate) for safety glass (Plexiglas), or foamed poly (styrene) to be applied in coffee cups. Some advantages of radical polymerizations, with respect to other techniques, are the relative insensitivi...
متن کاملMacromolecular engineering by atom transfer radical polymerization.
This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiato...
متن کاملCompression, supramolecular organization and free radical polymerization of ethylene gas
At low pressure, ethylene gas consists of single translating and rotating molecules and behaves as an ideal gas. With decrease of free volume by compression, various rotating supramolecular particles are formed, which require less space for the movement: molecular pairs, bimolecules and oligomolecules. The appearance of a new kind of particles is manifested as a phase transition of the second o...
متن کاملEffect of Small Reaction Locus in Free-Radical Polymerization: Conventional and Reversible-Deactivation Radical Polymerization "2279
Abstract: When the size of a polymerization locus is smaller than a few hundred nanometers, such as in miniemulsion polymerization, each locus may contain no more than one key-component molecule, and the concentration may become much larger than the corresponding bulk polymerization, leading to a significantly different rate of polymerization. By focusing attention on the component having the l...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2018
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.201711105